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Patrick A. Carr Emeline Moreira Leonid Neymark Marc D. Norman Julien Mercadier 《Geostandards and Geoanalytical Research》2023,47(1):67-87
Laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) is used to compare the suitability of four cassiterite (SnO2) materials (SPG, Yankee, AY-4 and Jian-1), and three matrix-mismatched reference materials (NIST SRM 612, NIST SRM 614 and 91500 zircon) for normalisation of U-Pb and Pb-Pb isotope ratios in cassiterite. The excess variance of ages determined by LA-ICP-MS is estimated to be ±0.33% for 207Pb/206Pb vs. 208Pb/206Pb isochron ages and ± 1.8% and for U-Pb ages. Incorporation of this excess variance in cassiterite ages is necessary for realistic uncertainties. 207Pb-206Pb ages are advantageous for dating Precambrian cassiterite such as SPG compared with U-Pb ages as matrix effect on instrumental mass fractionation of Pb isotopes are generally considered to be minor. We note minor bias in 207Pb/206Pb vs. 208Pb/206Pb isochron ages (~ 0.6%) when using either the NIST SRM 614 or 91500 zircon reference materials and emphasise the requirement for uncertainty propagation of all sources of error and reference materials with comparable U and Pb mass fraction to the cassiterite. The 238U/206Pb isotopic ratios from normalisation to matrix-mismatched reference materials show varied results, which emphasises the need to use matrix-matched reference materials for calculating U-Pb ages. When cross-calibrated against each other, LA-ICP-MS U-Pb ages of the ca. 1535 Ma SPG, ca. 245 Ma Yankee and ca. 155 Ma Jian-1 cassiterites are all consistent with their ID-TIMS values. 相似文献
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Ch. E. Perret 《Aquatic Sciences - Research Across Boundaries》1924,3(1-2):1-86
Sans résumé
Ce travail a obtenu le Prix Léon Du Pasquier 1924. 相似文献
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The hydraulic integrity of aquitards is generally assumed and relies on a few core-scale permeability measurements, drill-stem tests, or textbook values. This approach is because hydraulic data across the full aquitard thickness is generally lacking. Proper assessment of aquitard integrity should be studied at the formation (spanning its entire thickness at a single point) or regional (formation properties at multiple locations throughout the basin) scale. One formation-scale approach uses environmental tracers and advection-dispersion modeling to constrain fluid flow rates. This study demonstrates the use of helium concentrations in quartz as a method of constraining the rate of fluid flow in a 520-m thick aquitard in the Gunnedah Basin, NSW, Australia. Quartz was separated from existing core samples in the Watermark and Porcupine Formations at depths from 750 to 1200 m. The helium was released from these samples by heating and select samples were impregnated with helium to determine the rate of helium diffusion through the quartz. One-dimensional advection-dispersion modeling of the helium profile accounting for diffusive helium exchange between quartz and pore water revealed, that (1) vertical fluid velocity has been on the order of 0.02 mm/year or less for tens to thousands of years, (2) helium is in equilibrium between quartz and pore water, and (3) the helium profile is transient indicating that helium concentrations in the underlying Maules Creek Formation has varied over geological time. Further modeling identified aquitard conditions (thickness and temperature) for which equilibrium exists, a precondition for deriving formation-scale permeability. 相似文献
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Modelling considerations for examining the mean and unsteady flow in a simple urban-type street canyon 总被引：3，自引：0，他引：3
With very few exceptions, just about all limited area models (LAMs) used in operational NWP and regional climate modeling use the Davies (Q J R Meteorol Soc 102:405–418, 1976) relaxation lateral boundary conditions (LBCs), even though they make no effort to respect the basic mathematics of the problem. While in the early stages of the primitive equation LAM development in the seventies numerous schemes have been proposed and tested, LAM communities have eventually for the most part settled on the relaxation LBCs with few questions asked. An exception is the Eta model used extensively at NCEP and several other centers, in which the Mesinger (Contrib Atmos Phys 50:200–210, 1977) LBCs are used, designed and based on knowledge available before the introduction of the relaxation scheme. They prescribe variables along the outermost row of grid points only; all of them at the inflow points and one less at the outflow points where the tangential velocity components are extrapolated from inside of the model domain. Additional schemes are in place to suppress separation of gravity-wave solutions on C-subgrids of the model’s E-grid. A recent paper of Veljovic et al. (Meteor Zeitschrift 19:237–246, 2010) included three 32-day forecasts done with both the Eta and the relaxation LBCs and the comparison of some of their verification results. Here we extend this experiment by three additional forecasts to arrive at an ensemble of six members run with both schemes, and present a more complete discussion of results. We in addition show results of one of these forecasts in which the linear change of relaxation coefficients was replaced by the change following the recommendation of Lehmann (Meteorol Atmos Phys 52:1–14, 1993). We feel that the results of our two verification schemes strongly suggest the advantage of the Eta over the conventional relaxation scheme, thereby raising doubts as to the justification for its use. 相似文献
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Abstract The development of statistical relationships between local hydroclimates and large-scale atmospheric variables enhances the understanding of hydroclimate variability. The rainfall in the study basin (the Upper Chao Phraya River Basin, Thailand) is influenced by the Indian Ocean and tropical Pacific Ocean atmospheric circulation. Using correlation analysis and cross-validated multiple regression, the large-scale atmospheric variables, such as temperature, pressure and wind, over given regions are identified. The forecasting models using atmospheric predictors show the capability of long-lead forecasting. The modified k-nearest neighbour (k-nn) model, which is developed using the identified predictors to forecast rainfall, and evaluated by likelihood function, shows a long-lead forecast of monsoon rainfall at 7–9 months. The decreasing performance in forecasting dry-season rainfall is found for both short and long lead times. The developed model also presents better performance in forecasting pre-monsoon season rainfall in dry years compared to wet years, and vice versa for monsoon season rainfall. Editor Z.W. Kundzewicz Citation Singhrattna, N., Babel, M.S. and Perret, S.R., 2012. Hydroclimate variability and long-lead forecasting of rainfall over Thailand by large-scale atmospheric variables. Hydrological Sciences Journal, 57 (1), 26–41. 相似文献
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Caroline Avril Valérie Malavergne Razvan Caracas Brigitte Zanda Bruno Reynard Emeline Charon Ema Bobocioiu Fabrice Brunet Stephan Borensztajn Sylvain Pont Martine Tarrida François Guyot 《Meteoritics & planetary science》2013,48(8):1415-1426
Raman spectra were acquired on a series of natural and synthetic sulfide minerals, commonly found in enstatite meteorites: oldhamite (CaS), niningerite or keilite ((Mg,Fe)S), alabandite (MnS), troilite (FeS), and daubreelite (Cr2FeS4). Natural samples come from three enstatite chondrites, three aubrites, and one anomalous ungrouped enstatite meteorite. Synthetic samples range from pure endmembers (CaS, FeS, MgS) to complex solid solutions (Fe, Mg, Ca)S. The main Raman peaks are localized at 225, 285, 360, and 470 cm?1 for the Mg‐rich sulfides; at 185, 205, and 285 cm?1 for the Ca‐rich sulfides; at 250, 370, and 580 cm?1 for the Mn‐rich sulfides; at 255, 290, and 365 cm?1 for the Cr‐rich sulfides; and at 290 and 335 cm?1 for troilite with, occasionally, an extra peak at 240 cm?1. A peak at 160 cm?1 is present in all Raman spectra and cannot be used to discriminate between the different sulfide compositions. According to group theory, none of the cubic monosulfides oldhamite, niningerite, or alabandite should present first‐order Raman spectra because of their ideal rocksalt structure. The occurrence of broad Raman peaks is tentatively explained by local breaking of symmetry rules. Measurements compare well with the infrared frequencies calculated from first‐principles calculations. Raman spectra arise from activation of certain vibrational modes due to clustering in the solid solutions or to coupling with electronic transitions in semiconductor sulfides. 相似文献
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Professeur Dr. Raymond Mirouse Gilbert Barrouquère Gilbert Bessière Jean-Jacques Delvolvé Marie-France Perret 《International Journal of Earth Sciences》1983,72(1):253-281
Conodont associations and recent macrofaunal discoveries, allow us to date the beginning of detrital deposits going with the Variscan uplift in the Pyrenean marine basins during the Lower Carboniferous. Thus, the establishing of synorogenic conditions seems to have progressed from the East to the West; there appears the picture of a kind of north-Pyrenean axis already individualized in the wide Cantabrico-Pyrenean foreland. 相似文献
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Peter Perret Dieter Imboden K. Wuhrmann 《Aquatic Sciences - Research Across Boundaries》1976,38(1):63-64
Ohne Zusammenfassung 相似文献